Polyphenols identified by photo diode array-HPLC (PDA-HPLC) in 20 apple varieties

NumbertR (min)Polyphenol compoundFormula
P111.17Neochlorogenic acidC16H18O9
P214.77CatechinC15H14O6
P317.25Chlorogenic acidC16H18O9
P420.25p-Coumaroylquinic acidC16H18O8
P520.94Caffeic acidC9H8O4
P622.79EpicatechinC15H14O6
P723.30Caffeoylquinic acid isomerC16H18O9
P824.32Kaempferol-hexosideC27H30O15
P929.95Coumaric acidC9H6O3
P1030.89Ferulic acidC10H10O4
P1137.50Protocatechuic acidC7H6O4
P1238.29Quercetin 3,5-digalactosideC27H30O17
P1338.77RutinC27H30O16
P1439.63Caffeoyl hexosideC15H18O9
P1540.68PhlorizinC21H24O10
P1641.42Syringic acidC9H10O5
P1741.94Naringenin-7-hesperidosideC27H32O14
P1842.82Procyanidin A-type trimerC45H36O18
P1943.53Procyanidin B-type trimerC45H36O18
P2045.08Quercetin rutinosideC27H30O16
P2145.40Quercetin-3-O-deoxyhexosyl(1-2) deoxyhexosideC27H30O15
P2245.58Quercetin-3-O-pentosyl-7-O-hexosideC26H28O16
P2345.80PhloretinC15H14O5
P2446.213-HydroxyphloretinC15H14O6
P2546.48Phloretin 2’-O-rhamnosideC21H24O9
P2646.76Shikimic acidC7H10O5
P2747.11Quercetin-3-O-pentosyl-pentosideC25H26O15
P2847.81Procyanidin B-type dimerC30H26O12
P2948.14Procyanidin A-type dimerC30H24O12
P3048.433-Hydroxyphloretin-pentosyhexosideC21H24O11
P3149.04Quercetin 3-O-(6’’-acetyl-glucoside) C23H22O13

tR: retention time