From:  Functional lignin hydrogels for biosensors and biomedical therapy

 The various applications of lignin-based hydrogels in wound healing.

MaterialPreparation methodFunction/activityTarget pathogenFindingsReference
Lignin-graft polyoxazoline conjugated triazolePolymerization & covalent modificationAnti-biofilm activity, anti-inflammatoryPseudomonas aeruginosaBiofilm activity: reduction in thickness of biofilm structure from 30 nm to 8 nm (treated) after 12 h incubation; anti-inflammatory: inhibits LPS-induced iNOs, IL-1β, TNF-alpha α[116]
Lignin-based hydrogelSolid state esterification with PEG and poly (methyl vinyl ether-co-maleic acid)Anti-microbialStaphylococcus aureus, Proteus mirabilisSignificant reduction in bacterial adherence observed (up to 5-log)[117]
Ag-Lignin NPs-PAA-pectin hydrogelFormulation of Ag-lignin nanoparticles followed by polymerization with pectin and acrylic acidAnti-bacterial, wound healingStaphylococcus epidermidis, Escherichia coliBactericidal ratio of hydrogel for Staphylococcus epidermidis and Escherichia coli was found to be 98% and 97%, respectively. Healing ratio found to be 90%[118]
AgNPs-lignin hydrogelCrosslinking and in-situ gelationAnti-microbialStaphylococcus aureus, Escherichia coliComplete bactericidal inhibition at high concentration (up to 108 cfu/mL)[29]
Lignin-MA/SBMA double network hydrogelFree radical polymerization of SBMA and lignin-MAAntimicrobial, anti-foulingStaphylococcus aureus, Escherichia coli40% lignin -MA hydrogel showed 94.8% reduction of Escherichia coli and 95.7% reduction of Staphylococcus aureus[119]
Lignosulfonate-PVC composite hydrogelCovalent interaction (hydrophobic) induced gelation (i.e., physical crosslinking)Self-wound healing, tissue adhesivenessRat liver bleeding model: bleeding decreased from 196.7 mg to 29.4 mg (treated) within 60 s. Strong adhesion of 41.3 kPa to liver tissue[120]
OTC-loaded lignin chitosan bio composite hydrogelFreeze thaw method (5 cycles)Antibacterial, wound healing, antioxidantStaphylococcus aureus, Escherichia coliStrong antibacterial activity: zone of inhibition found to be 2 mm (Escherichia coli) and 24.5 mm (Staphylococcus aureus). Antioxidant activity: 39.3% RSA (at 50 mg)[92]
PVA-CS-EGCG hydrogelAnti-bacterial, wound healingPseudomonas aeruginosa, Staphylococcus aureus, Listeria monocytogenes, Salmonella TyphimuriumAntibacterial (MIC/MBC): effective inhibition and bactericidal effect at 0.22–0.88 mg/mL against pathogens[121]